MPC II year

MPC Second Year

Chemistry – SyllabusIntermediate Course – II Year
Chemistry (Theory)

1. A Group Elements:

1.1 V A group elements – Nitrogen and Phosphorus General characteristics with special reference to Hydrides, Oxides, Halides, Structural aspect of Oxy-acids.
1.2 Preparation and uses of Ammonia and super-phosphate.

2. A Group Elements:

2.1 Oxygen and sulphur – Allotropy – General characteristics with special reference to Hydrides, Oxides (SO 2 , SO 2.2 Halides, Structural aspect of Oxy acids.
2.3 Preparation and properties of Ozone and Sodium thiosulphate.

3. A Group Elements:

3.1 General characteristics of Halogens.
3.2 Preparation, properties and uses of fluorine and chlorine.
3.3 Oxides and oxy-acids of chlorine only (only structural treatment and oxidation states).
3.4 Preparation, properties and uses of Bleaching Powder.

4. Transition-Elements (D-Block Elements):

Definition – General characteristics of 3d series with special reference to variable Oxidation states, magnetic properties, colour, formation of alloys and complex compounds – Werner’s theory.

5. Solutions

5.1 Methods of expressing concentration of solutions – Molarity, Molality, normality and mole fraction.
5.2 Vapor pressure-effect of temperature on Vapor pressure-Vapor pressure and Boiling point. Relative lowering of vapour pressure-Raoult’s law (elementary treatment).

6. Acids And Bases:

6.1 Theories of Acids and Bases Lowry – Bronsted concept Lewis theory of acids and bases.
6.2 Ionic product of water, PH, Buffers – Numerical problems on these, Indicators – Choice of indicators, PH-range and uses.
6.3 Salt hydrolysis – Types of hydrolysis with examples.

7. Chemical Kinetics, Chemical Equilibrium And Energetics:

7.1. Concepts of reaction rate, factors affecting reaction rates, Rate law, rate constant and its units. Order and Molecularity – First order rate equation and half life – Collission Theory of reaction rate (No derivation).
7.2. Reversible and Irreversible reactions. Concept of chemical equilibrium – Law of Mass Action – chemical equilibrium-Kc, Kp and their relationship with respect to Ammonia and Sulphur Trioxide.
7.3. Lechatelier’s Principle and its application to the industrial processes like Ammonia and Sulphur Trioxide.
7.4. Thermo chemistry: Exothermic and Endothermic reactions with examples – Heat of reaction (the relation between DE and DH) Combustion, formation, solution and neutralization – Hess’s law of constant heat summation

8. Electro-Chemistry:

8.1. Electrolytes and Non-electrolytes.
8.2. Faraday’s laws of electrolysis.
8.3. Galvanic & Voltaic cells – representation8.4 Nernst equation (No derivation) – e.m.f. calculations.

9. Nuclear Chemistry:

9.1. Composition of Nucleus – Isotopes, Isotones, Isobars, Isodiapheres, Nuclear stability – Factors effecting Nuclear stability, mass defect, binding energy, Average binding energy, N/P ratio, Magic Numbers).
9.2. Radio-active disintegration and its rate-Half-life and average life.
9.3. Natural and artificial radio-activity, disintegration series-Group displacement law-Types of Nuclear reactions (fission and fusion)-Differences between Nuclear and Chemical reactions- Radio-active isotopes and their applications Idoine 131 , Cobalt 60 , Sodium 24 , C 14 and P 30 .

10. Surface Chemistry :

10.1. Adsorption and absorption. Physical and chemical adsorption-distinguishing properties-Adsorption of gases on Metals Adsorption from solutions (Elementary treatment).
10.2. Colloidal state:- True and colloidal solutions – Explanation of the terms – Dispersion medium, dispersed phase, Iyo-phillic and Iyo-phobic sols using the examples; smoke, cloud, blood, milk, starch solution and gold sol.
10.3. Emulsions:- Emulsifying agent and emulsification – its applications. Micelles – cleansing action of soap.
123456789
10.4. Catalysis – Explanation of the terms – Homogeneous and Hetero-generous catalysis – distinctions with suitable Examples-auto-catalysis with one example.

11. Carbon Compounds

11.1. Alkyl Halides – Nomenclature-Preparation, properties and uses of Ethyl chloride and chloroform.
11.2. Oxygen compounds:- Nomenclature of Alcohols, Ethers, Aldehydes, Ketones and Carboxylicacids. Preparation, properties and uses of Ethyl Alcohol, Diethyl ether, Acetaldehyde, Acetoneand Acetic acid.
11.3 Nitro-compounds-Nomenclature of Amines and Nitro-compounds- Preparation, Properties and uses of Nitro-benzene and aniline.

12. Chemistry In Biology And Medicine:

12.1. Brief Survey on the importance of Metals in the bio-molecules viz., Hemoglobin Cyanocobalamin(Vitamin Bl2) and Chlorophyll-basic structure, function of metal ions and uses.
12.2. Common drugs used in Medicine-Acetyl Salicylic Acid (Aspirin)-Paracetamol, Methyl Salicylate (Oil of winter green) preparation and uses only.

Intermediate II Year - Mathematics IIA (Algebra And Probability)

Algebra

1) Quadratic Expressions
2) Theory of Equations
3) Matrices
4) Permutations and Combinations
5) Binomial Theorem
6) Partial fractions
7) Exponential and Logarithmic series

Probability

8) Probability
9) Random variable and distributions

[ Top ]

Intermediate Ii Year -Mathematics Ii (B)(Co-Ordinate Geometry And Calculus)

Co-Ordinate Geometry And Calculus

1) Circles
2) Systems of circles
3) Parabola
4) Ellipse
5) Hyperbola
6) Polar co-ordinates

Calculus

7) Successive Differentiation
8) Integration
9) Definite Integration
10) Numerical Integration
11) Differential Equations

Intermediate Ii Year - Physics

I. Sound

Characteristics of a sound note – Formation of stationary waves in stretched strings – Laws of vibrating strings – Experimental verification by Sonometer – Beats – Definition and explanation – Doppler Effect – Derivation of formula for apparent frequency in specific cases – Applications and limitations of Doppler Effect – Echoes – Absorption of sound waves – Reverberations – Fundamentals of Building acoustics – Statement of Sabine’s formula (Qualitative treatment only).

II. Ray Optics And Optical Instruments

Nature of light – Newton’s corpuscular theory – Huygens's wave theory – Electromagnetic wave theory, Properties of Electro-magnetic waves – Quantum theory (Elementary ideas only) –– Critical angle – Total internal reflection – Application to Optical fibres. Len’s Maker’s for-mula 1/f = (m - 1) (1/R 1 + 1/R 2 ) (expression only) – Defects of images – Spherical and Chromatic aberrations and their elimination (Qualita-tive treatment) – Construction of Ramsden’s and Huygens's eyepieces. Dispersion of light – Dispersive Power – Pure and impure spectra – Conditions for obtaining pure spectrum. Different kinds of spectra – Emission spectra-line, band and continuous spectra; Absorption spectra – Their significance; Fraunhofer lines and their significance.

III. Physical Optics

Interference – Coherent sources – young’s double slit experiment – Applications – Diffraction – phenomenon of diffraction – Fresnel and Fraunhofer Diffraction – Applications - Polarization – concepts of polarisation – production of plane polarized light by reflection, refraction and double refraction (Polaroids).

IV. Magnetism

Coulomb’s inverse square law – Couple acting on a bar magnet placed in a uniform magnetic field – Magnetic moment of a magnet – Expression for Magnetic induction due to a bar magnet on axial and Equatorial lines – Superposition of magnetic fields – Tangent law – Deflection Magnetometer – Comparison of magnetic moments in Tan-A and Tan-B positions by Equal distance method and null method – Verification of Inverse square law; vibration Magnetometer – Experimental determination of M and H.

V. Electrostatics

Coulomb’s Law – Permittivity – concept of electric field – Electric lines of force – Force on a charge in an electric field (F=Eq) – Electric potential – Potential due to point charge – potential energy of a point charge in a uniform electric field – electron volt – relation between E and V (E=V/d). Capacitance – Dielectric constant – Parallel plate capacitor – mention of formula for capacitance – di-electric materials (Elementary treatment) - effect of di-electric on capacity (Expressions only) – derivation of formulae for resultant capacitance, when capacitors are connected in series and parallel – Energy stored in a capacitor – effect of dielectric on theenergy – types of capacitors and their uses.

VI. Current Electricity

Ohm’s Law – Ohmic and non-ohmic resistances – specific resistance – conductance – temperature dependence of resistivity – thermistor – emf of a cell – internal resistance and back e.m.f. Kirchoff’s laws – statement and explanation – application to wheat stone’s bridge for its balance conditions – metre bridge – principle of potentiometer – Comparison of e.m.f. of cell – determination of internal resistance of a primary cell - Series and parallel combination of cells.

VII. Thermoelectricity

See beck effect – peltier and Thomson effects and their coefficients – variation of thermo e.m.f. with temperature – Neutral and inversion temperatures – application of thermo couples.

VIII. Electromagnetics

VII. Oersted’s experiment – Biot-Savart law – Ampere law – magnetic field near a long straight wire and at the centre of a circular coil carry-ing current (expressions only) – Tangent galvanometer principle and working – force on a moving charge in a magnetic field – f=(q.VxB) – force on a current carrying conductor in a magnetic field – force between two straight parallel conductors carrying current – definition of ampere – Fleming’s left hand rule-force and torque on current loop in a magnetic field – construction and working of a moving coil galvanometer – shunt and its uses – conversion of moving coil galvanometer into ammeter and voltmeter – Comparison of MCG with T.G. Electromagnetic induction – Magnetic flux and induced emf-Faraday and lenz’s laws – Fleming’s right hand rule – self and mutual inductance – Henry – Principle of transformer (Elementary ideas). a.c. current circuits – Introduction – Instantaneous, maximum and r-msvalues of a.c current – growth and decay of current in an inductor – growth and decay of charge in a capacitor – A.C. Circuits – L.C, C.R. and L.C.R. circuits.

IX. Atomic Physics

Discovery of electron-e/m of electron by Thomson’s method – charge of an electron by Millikan’s oil drop method (Principle only). Photoelectric effect-laws of photo electric emission – Einstein’s Pho-toelectric equation and its experimental verification by Millikan’s method – photo electric cells and their uses. X-ray spectra – Mosley’s law and its importance – Compton effect –dual nature of matter – DeBroglie’s hypothesis (concepts only)

X. Nuclear Physics

Composition of nucleus – nuclear forces – mass defect and binding energy (Explanations with examples) – artificial transmutation of eleents – Discovery of neutron – nuclear fission – chain reaction – Principle and working of a nuclear reactor – Radio-Isotopes and their uses – Nuclear radiation hazards – Protective shielding – Nuclear fusion – energy of the sun and the stars (Carbon – Nitrogen cycle and Proton – Proton cycle) – elementary particles.

XI. Semi-Conductor Devices

Junction diode – depletion layer – barrier potential – forward and re-verse bias – current – voltage characteristics – junction diode as half wave and full wave rectifiers – Zener diode as Voltage regulator. Transistors pnp and npn transistors – Transistor characteristics - Tran-sistor amplifier (common emitter).

[ Top ]